Chemometric investigation of barley and malt data

KARL J. SIEBERT (1), Aleksander Egi (2), Robert McCaig (2)
(1) Cornell University, Geneva, NY; (2) Canadian Malting Barley Technical Centre, Winnipeg, MB, Canada

Barley samples were pilot malted at the Canadian Malting Barley Technical Centre, where analyses of the barleys and malts were performed. The barley data contained 8 observations each for approx. 360 samples; 14 cultivars and 9 crop years were well represented. Principal components analysis (PCA) applied to this data found three significant PCs, indicating that the 8 measurements actually contained information on three fundamental properties. The first PC was heavily influenced by assortment and 1,000-kernel weight. The second PC was influenced positively by germination and negatively by moisture content. The third PC was mainly related to protein content. Pattern recognition procedures were partially successful in classifying barley samples by cultivar or crop year. When 14 measurements for 538 malt samples were analyzed with PCA, it appeared there were five fundamental properties. The first PC was heavily influenced negatively by friability and positively by β-glucans, viscosity, and fine/coarse difference; essentially, this represents modification. The second component was mainly influenced by α-amylase and diastatic power and the third by both fine and coarse extract. The fourth PC was influenced positively by soluble protein and wort color and negatively by wort pH. The fifth PC was heavily influenced by Kolbach index and free amino nitrogen. Relationships between the barley and malt samples were sought using partial least squares regression.

Karl Siebert received a Ph.D. degree in biochemistry from Penn State in 1970. He then joined the Stroh Brewery Company in Detroit, MI, where he spent 18 years and held positions ranging from research associate to director of research. In 1990, Karl joined Cornell University as a professor of biochemistry in the Department of Food Science and Technology. He served five years as department chair and now has a predominantly research commitment. Karl is active as a consultant in beverage technology and chemometrics. He twice received MBAA Presidential Awards for papers he presented, and he and his colleague, Penny Lynn, received the ASBC Eric Kneen Memorial Award (for the best paper in the ASBC Journal in the prior year) three times. Karl was made an Honorary Professor of the Moscow (Russia) State Academy of Food Processing in 1996, and in 1999 he received the ASBC Award of Distinction. He is currently a member of the ASBC Journal Editorial Board and the ASBC Foundation Board. Karl’s research interests involve foam and haze in beverages, perception of astringency and other flavors, the application of chemometric methods in food science, and assessment of microbiological risk.

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