A comparative study of the functionality of hop hard resins extracted from different hop varieties

CYNTHIA ALMAGUER (1), Thomas Becker (1), Martina Gastl (1)
(1) Technische Universität München-Weihenstephan, Lehrstuhl für Brau- und Getränketechnologie, Freising, Germany

At its most simple, hop (Humulus lupulus L.) varieties are classified, according to their flavoring properties, as ‘bittering hops’ and ‘aroma hops’. In numerous studies, detailed assessments of the quality parameters of both types have been carried out. Usually, bittering hops and aroma hops are compared and rated based on their brewing value and their contributions to beer quality. The brewing value of hops is primarily attributed to the flavor- and bitter-active compounds found in the resins. These resins are synthesized and accumulated in the lupulin glands of hops. Early work on the fractionation of hop resins, based on the solubility of resins in various organic solvents, classified them into soft resins and hard resins. Until now, research has primarily focused on studying the impact on beer properties of the major hop bitter acids (α- and β-acids) present in the soft resin. For this reason, little information is available on the functionality of the hard resin and for years it has been considered of no value. However, it is known that, besides the α-acids, hops contain other constituents which can contribute to beer quality. It is the purpose of this work to determine the extent to which the hard resins contribute to the beer quality. Additionally, it is intended to establish if there are any significant differences among the hard resins extracted from the different hop varieties. Further, the functionality of this resin as a brewing product is examined, and finally the hard resin contribution to the microbiological stability of beer is assessed. To achieve all these, brewing trials were conducted in which the α-acids were replaced with a hard resin rich extract. In these laboratory-scale experiments, it was possible to determine that the hard resin contributes to the microbiological stability of beer. Furthermore, it was shown that addition of this resin confers a pleasant bitterness and a desired hoppy flavor which is a great contribution to the harmony and drinkability of beer.

In 2008, Cynthia Almaguer completed her B.S. degree in biochemical engineering at Jacobs University, Bremen. She then started her graduate studies in a collaborative project between the Institute of Brewing and Beverage Technology (Professor Thomas Becker), TUM-Weihenstephan and the Department of Food and Nutritional Sciences (Professor Elke Arendt), University College Cork. Her research project aims to understand and reveal the contributions of hop hard resins in beer. A significant portion of her research activities are directed toward the investigation of the taste as well as the antimicrobial properties of hops.