P-12

Impact of esterase activity in cold-filtered beer.
PETR VESELY, Antonia Volgyi, Lance T. Lusk, Alfonso Navarro, John Seabrooks, and David Ryder. Miller Brewing Company, Milwaukee, WI.

An extracellular yeast esterase found in unpasteurized beer hydrolyzes long chain esters such as ethyl hexanoate and ethyl octanoate. The enzyme is competitively inhibited by the presence of octanoic acid. Esterase activity reaches a maximum at day 2-3 of fermentation, declines, and then returns to the maximum at EOF as beer temperature decreases. Pasteurization destroys the activity, but esterase remains active in cold-filtered beer. Lower levels of total esters and higher levels of total fatty acids were found in cold-filtered beer stored at 30 C. A correlation was observed between ethyl hexanoate and hexanoic acid in the stored cold-filtered beer. Octyl acetate, which significantly decreased in cold-filtered beer during storage at 30 C, was a good esterase activity indicator. The impact of esterase activity on sensory evaluation is minimal as the changes in levels of esters and acids were individually below the level of sensory detection.

Petr Vesely is pursuing Ph.D. studies at the Institute of Chemical Technology in Prague, Czech Republic. His Ph.D. research topic is "Factors influencing beer aging". In 2000, he performed research at the Institute Meurice, Brussels, Belgium, with a European Union scholarship, Erasmus Exchange Program. In 2001, he completed an internship at the Miller Brewing Company. Petr has also been a brewer at the Hideji Brewery, Nobeoka City, Miyazaki prefecture, Japan.

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