O-10

Astringent evaluation methods of beverages using a quartz-crystal microbalance.
HIROTAKA KANEDA (1), Junji Watari (1), Masachika Takashio (1), and Yoshio Okahata (2). (1) Brewing Research Laboratories, Sapporo Breweries, Ltd., Yaizu-City, Shizuoka, Japan, and (2) Department of Biomolecular Engineering, Tokyo Institute of Technology.

Although astringency plays an important role in beer taste, body and smoothness, there have been very few reports on the measurement method for beer astringency. The aim of this study is to develop objective evaluation methods for the astringency of beverages using a quartz crystal microbalance (QCM). It has been thought that stimuli of the complexes of tannins with salivary proteins to the oral membrane cause the astringent sensations such as drying, shrinking, drawing and puckering of the epithelium. We tried to develop two measuring methods for the astringency of beverages using the QCM, a measurement of reactivity of tannins with proteins using the protein-immobilized QCM and a measurement of the interaction of tannin/peptide complexes with a lipid membrane using the lipid-coated QCM. We found that polyphenols specifically bind with gelatin and that the adsorption of astringent tannins on the lipid membrane significantly increases in the presence of peptides, while NaCl (salty taste), tartaric acid (sour taste), quinine-sulfite (bitter taste), isohumulones (bitter taste), sucrose (sweet taste), and glutamic acid (umami taste) had no effect. It seems that the adsorption of tannin-peptide complexes on the oral lipid membrane could be involved the astringent sensation. The adsorption of red wine, Japanese green tea or beer on the lipid membrane in the presence of bovine serum albumin or gelatin successfully agreed with the astringent intensity in the sensory evaluation.

Hirotaka Kaneda graduated from Kyushu University in 1984 with a M.S., and then joined Sapporo Breweries, Ltd. He is currently a senior researcher in the Brewing Research Laboratories. He worked on beer stability and received his Ph.D. at Nagoya University in 1994. He studied human-brain function in gustation and olfaction in the National Institute of Bioscience and Human-Technology from 1996 to 2000. He received the Eric Kneen Memorial Award from the American Society of Brewing Chemists in 1995 and the Technical Award from the Agricultural Chemical Society of Japan in 2000.

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