P-3

Special malts and beer aging: How to reach high antioxidant activity and low intrinsic nonenal potential.
Catherine Liégeois and SONIA COLLIN, Université catholique de Louvain, Unité de brasserie et des industries alimentaires, Croix du Sud 2/Bte 7, B-1348 Louvain-la-Neuve, Belgium.

As previously described (Lermusieau et al. J. Am. Soc. Brew. Chem. 1999, 57, 29-33; Noël et al. J. Agric. Food Chem. 1999, 47, 4323-4326), the nonenal potential found in the wort before fermentation is a good indicator of beer staling. It derives from the retention of trans-2-nonenal by wort amino acids and proteins. The so-obtained adduct protects trans-2-nonenal from yeast reduction activity but can release it by acidic hydrolysis, mainly when the beer pH is low or the storage temperature inadequate. Although auto-oxidation in the boiling kettle revealed to be the limiting factor for staling, recent results clearly indicate that malt kilning is another significant source of nonenal potential. Of course, due to the presence of melanoidins, caramel malt (10%) brings a higher antioxidant activity to the wort. However, despite a low lipoxygenasic activity during mashing and a low auto-oxidation during boiling, this wort will be characterized by a higher nonenal potential. In the present work, different kilning temperatures will be compared in terms of malt reducing power and/or nonenal potential. The fate of trans-2-nonenal added just after germination will be also discussed.

Sonia Collin. PhD. in Chemical Sciences from the University of Namur, Belgium (1988). Professor of Malting and Brewing Sciences at the Université catholique de Louvain, Louvain-la-Neuve, Belgium since 1993. She is currently Head of the Department of Brewery and Food Industries. She is a member of the American Society of Brewing Chemists and of the EBC Brewing Science Group. She has published more than 75 papers in scientific journals, mainly on flavor stability, sulfur aroma, pyrazines and hops. She was recently chairman of the IX th J. De Clerck Chair "The oxygen paradox in the brewing process" (2000).